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Beilstein J. Org. Chem. 2017, 13, 1807–1815, doi:10.3762/bjoc.13.175
Graphical Abstract
Figure 1: Isoprene as chemical building block in nature and organic synthesis.
Scheme 1: Pd-catalyzed dimerization of isoprene.
Scheme 2: Putative mechanism for the Pd(OAc)2-catalyzed dimerization of isoprene.
Scheme 3: Functionalization of the isoprene-dimer 2-TT to substituted O- and N-heterocycles.
Beilstein J. Org. Chem. 2007, 3, No. 25, doi:10.1186/1860-5397-3-25
Scheme 1: General synthesis of sulfonimidamides 3 from sulfinamides 1.
Scheme 2: Synthesis of N-benzoyl sulfonimidamides 3a.
Scheme 3: Cleavage of the N-benzoyl group.